Experimental analysis of arsenic precipitation during microbial sulfate and iron reduction in model aquifer sediment reactors   总被引：4，自引：0，他引：4  

Matthew F. Kirk  Eric E. Roden  Adrian J. Brealey 《Geochimica et cosmochimica acta》2010,74(9):2538-6788

Microbial SO₄²⁻ reduction limits accumulation of aqueous As in reducing aquifers where the sulfide that is produced forms minerals that sequester As. We examined the potential for As partitioning into As- and Fe-sulfide minerals in anaerobic, semi-continuous flow bioreactors inoculated with 0.5% (g mL⁻¹) fine-grained alluvial aquifer sediment. A fluid residence time of three weeks was maintained over a ca. 300-d incubation period by replacing one-third of the aqueous phase volume of the reactors with fresh medium every seven days. The medium had a composition comparable to natural As-contaminated groundwater with slightly basic pH (7.3) and 7.5 μM aqueous As(V) and also contained 0.8 mM acetate to stimulate microbial activity. Medium was delivered to a reactor system with and without 10 mmol L⁻¹ synthetic goethite (α-FeOOH). In both reactors, influent As(V) was almost completely reduced to As(III). Pure As-sulfide minerals did not form in the Fe-limited reactor. Realgar (As₄S₄) and As₂S₃(am) were undersaturated throughout the experiment. Orpiment (As₂S₃) was saturated while sulfide content was low (∼50 to 150 μM), but precipitation was likely limited by slow kinetics. Reaction-path modeling suggests that, even if these minerals had formed, the dissolved As content of the reactor would have remained at hazardous levels. Mackinawite (Fe_1 + xS; x ? 0.07) formed readily in the Fe-bearing reactor and held dissolved sulfide at levels below saturation for orpiment and realgar. The mackinawite sequestered little As (<0.1 wt.%), however, and aqueous As accumulated to levels above the influent concentration as microbial Fe(III) reduction consumed goethite and mobilized adsorbed As. A relatively small amount of pyrite (FeS₂) and greigite (Fe₃S₄) formed in the Fe-bearing reactor when we injected a polysulfide solution (Na₂S₄) to a final concentration of 0.5 mM after 216, 230, 279, and 286 days. The pyrite, and to a lesser extent the greigite, that formed did sequester As from solution, containing 0.84 and 0.23 wt.% As on average, respectively. Our results suggest that As precipitation during Fe-sulfide formation in nature occurs mainly in conjunction with pyrite formation. Our findings imply that the effectiveness of stimulating microbial SO₄²⁻ reduction to remediate As contamination may be limited by the rate and extent of pyrite formation and the solubility of As-sulfides.  相似文献   

Probable Neolithic footprints preserved in inter-tidal peat at Kenfig, South Wales (UK)     

Matthew R. Bennett  Silvia Gonzalez  Jason Kirby 《Proceedings of the Geologists' Association. Geologists' Association》2010,121(1):66-76

Holocene footprints have been reported from several locations around the UK coast preserved within inter-tidal sediments. These sediments are normally fine-grained silts, sands and clays. Here we report potential human footprints preserved in the lower of two inter-tidal peat units exposed on the foreshore at Kenfig in South Wales. The lower peat layer pre-dates 3810 ± 40 BP and its maximum age is constrained by two dates, one of 4930 ± 50 BP and another of 5110 ± 50 BP. The prints may have formed at any point within this time interval. Both peat units formed in a salt marsh, or fen environment, as indicated by the analysis of both diatoms and pollen and have been tentatively assigned to the middle Wentlooge Formation within the Holocene lithostratigraphy established for the Severn Estuary Holocene sequence. The footprints were digitised using an optical laser scanner and are compared to other Holocene human footprints exposed on the Sefton Coast in North West England. In comparison the Kenfig prints have poor anatomical form which may be the result of both the substrate and post-depositional modification. The paper demonstrates the value of using optical laser scanning in the data capture and analysis of transitory archaeological and geological trace evidence.  相似文献   

Late Quaternary glaciation and equilibrium-line altitudes of the Mayan Ice Cap, Guatemala, Central America     

Alex J. Roy  Matthew S. Lachniet 《Quaternary Research》2010,74(1):1-7

The Sierra los Cuchumatanes (3837 m), Guatemala, supported a plateau ice cap and valley glaciers around Montaña San Juan (3784 m) that totaled ∼ 43 km² in area during the last local glacial maximum. Former ice limits are defined by sharp-crested lateral and terminal moraines that extend to elevations of ∼ 3450 m along the ice cap margin, and to ca. 3000-3300 m for the valley glaciers. Equilibrium-line altitudes (ELAs) estimated using the area-altitude balance ratio method for the maximum late Quaternary glaciation reached as low as 3470 m for the valley glaciers and 3670 m for the Mayan Ice Cap. Relative to the modern altitude of the 0°C isotherm of ∼ 4840 m, we determined ELA depressions of 1110-1436 m. If interpreted in terms of a depression of the freezing level during maximal glaciation along the modern lapse rate of − 5.3°C km^− 1, this ΔELA indicates tropical highland cooling of ∼ 5.9 to 7.6 ± 1.2°C. Our data support greater glacial highland cooling than at sea level, implying a high tropical sensitivity to global climate changes. The large magnitude of ELA depression in Guatemala may have been partially forced by enhanced wetness associated with southward excursions of the boreal winter polar air mass.  相似文献   

Neoproterozoic chemostratigraphy   总被引：3，自引：0，他引：3  

Galen P. Halverson  Benjamin P. Wade  Matthew T. Hurtgen  Karin M. Barovich 《Precambrian Research》2010

Chemostratigraphy has diverse applications to investigating the rock record, such as reconstructing paleoenvironments, determining the tectonic setting of sedimentary basins, indirect dating, and establishing regional or global correlations. Chemostratigraphy is thus an integral component of many investigations of the ancient sedimentary record. In this contribution, we review the principle inorganic geochemical methods that have been applied to the Neoproterozoic sedimentary record. Analysis of the traditional stable and radiogenic isotope systems, such as δ¹³C, δ¹⁸O, δ³⁴S, and ⁸⁷Sr/⁸⁶Sr, is routine, particularly in successions rich in carbonate. These mainstay applications have yielded invaluable data and information bearing on the chronology and evolution of this eventful era in Earth history. Alongside the growing database of traditional data, a series of novel geochemical techniques have given rise to important new models and constraints on Neoproterozoic biogeochemical change. In particular, a range of proxies for water column redox, mainly obtained from black shales, have shed light on the pace and tempo of Neoproterozoic oxygenation and its link to the appearance of early animal evolution. Increased integration of diverse geochemical, sedimentological, and paleontological datasets, and the gradual radiometric calibration of the stratigraphic record promise to bring the details of the evolution of the Neoproterozoic Earth system into ever greater focus.  相似文献   

Assessing the response of watersheds to catastrophic (logging) and possible secular (global temperature change) perturbations using sediment-chemical chronologies     

David T. Long  Matthew J. Parsons  Catherine H. Yansa  Sharon S. Yohn  Colleen E. McLean  Ryan G. Vannier 《Applied Geochemistry》2010

Geochemical profiles of sediment cores from two oligotrophic lakes (Elk and Mullett) in northern Lower Michigan were studied to examine the response and recovery of watersheds to large-scale logging that occurred between 1850 and 1920. Specific questions addressed were: can the impact of extensive clear-cutting of forests be recognized in the sediment-chemical chronologies, can states of system stability be identified prior to the logging, and are there indications that the systems are recovering and possibly returning to a stable state? To answer these questions, elements were put into four groups as proxies for watershed runoff or export (e.g., Al, Mg), pollution (e.g., Pb, Cu), redox (e.g., Fe, As), and productivity (e.g., Ca, P). It was observed that vertical patterns of all proxies were influenced by logging and the early increases in concentration of pollution proxies were due to increased watershed export, not pollution. System stability might be recognized by relatively symmetrical vertical patterns among all of the proxies or secular changes of slowly increasing or decreasing vertical concentration trajectories. Some pre-logging trajectories were punctuated by episodes of slightly elevated concentrations that appear to be related to comparatively warmer periods during the Little Ice Age. Iron and Mn enrichments caused by increased watershed runoff might be misinterpreted as paleo-redox horizons. Results are interpreted to indicate that (1) reference conditions may be better defined as the temporal trends among proxy groups and not individual concentrations, (2) simply assuming pre-1800 conditions as a reference may not be appropriate, (3) inter-proxy group comparisons are needed to help for interpretations of intra-proxy group patterns, (4) the possible regime shift identified here might be expected for other ecosystems because of the intensity of human disturbances and secular changes, and (5) without consideration of a possible regime shift, recovery from logging is estimated to be on the order of 75–130 a, but shorter if regime shifts are considered.  相似文献   

The impact of over 100 years of wildfires on mercury levels and accumulation rates in two lakes in southern California,USA     

Sarah E. Rothenberg  Matthew E. Kirby  Broxton W. Bird  Margie B. DeRose  Chu-Ching Lin  Xinbin Feng  Richard F. Ambrose  Jennifer A. Jay 《Environmental Earth Sciences》2010,60(5):993-1005

In southern California, USA, wildfires may be an important source of mercury (Hg) to local watersheds. Hg levels and Hg accumulation rates were investigated in dated sediment cores from two southern California lakes, Big Bear Lake and Crystal Lake, located approximately 40-km apart. Between 1895 and 2006, fires were routinely minimized or suppressed around Big Bear Lake, while fires regularly subsumed the forest surrounding Crystal Lake. Mean Hg concentrations and mean Hg accumulation rates were significantly higher in Crystal Lake sediments compared to Big Bear Lake sediments (Hg levels: Crystal Lake 220 ± 93 ng g⁻¹, Big Bear Lake 92 ± 26 ng g⁻¹; Hg accumulation: Crystal Lake 790 ± 1,200 μg m⁻² year⁻¹, Big Bear 240 ± 54 μg m⁻² year⁻¹). In Crystal Lake, the ratio between post-1965 and pre-1865 Hg concentrations was 1.1, and several spikes in Hg levels occurred between 1910 and 1985. Given the remote location of the lake, the proximity of fires, and the lack of point sources within the region, these results suggested wildfires (rather than industrial sources) were a continuous source of Hg to Crystal Lake over the last 150 years.  相似文献   

Multi-zone fusion crust formation and classification of the 2004 Auckland meteorite (L6, S5, and W0)     

James M. Scott  Marianne Negrini  Kevin Faure  Marshall C. Palmer  Derek R. Knaack  Matthew I. Leybourne 《Meteoritics & planetary science》2023,58(3):328-340

On June 12, 2004, a meteorite passed through Earth's atmosphere and landed under the television in the living room of a house in Auckland, New Zealand. Textural characteristics, the chemistry of olivine (Fa_23–24) and orthopyroxene (Fs_20.7), and the bulk rock triple oxygen isotopes (δ¹⁷O + 3.1; δ¹⁸O + 4.2‰) from the interior of the completely unweathered (W0) 1.3 kg meteorite, hereafter referred to as Auckland, suggest it to be a strongly metamorphosed fragment from the interior of a low iron ordinary chondrite (L6) parent asteroid. The occurrence of maskelynite but shock fracturing of olivine and pyroxene indicates Auckland experienced extreme shock metamorphism (S5), likely during Ordovician fragmentation of the asteroid parent. The fusion crust consists of three zones: (1) an innermost zone containing narrow Fe-Ni-S-bearing veins that migrated along pre-existing shock fractures in olivine and pyroxene; (2) a middle zone in which the meteorite partially melted to form a silicate glass and immiscible blebs of metal and troilite, and is accompanied by unmelted silicate minerals; and (3) an approximately 0.1 mm wide vesicular-rich outermost layer that largely melted, volatilizing sulfides, before quenching to form glass and olivine. Oxygen isotope values of the bulk rock and/or maskelynite of melted rim and modified substrate are 2–3‰ greater than the meteorite interior and indicate that up to 19% of terrestrial atmospheric O₂ was incorporated into the fusion crust during the formation. The fusion crust migrated inwards as ablation occurred, enabling melting, migration, and re-precipitation ± loss of sulfide and metal components, with the prominent glassy rim therefore forming from an already chemically modified zone.  相似文献   

Ecological Modernization or Aristocratic Conservation? Exploring the Impact of Affluence on Carbon Emissions at the Local Level     

Andrew Pattison  Robert Habans  Matthew Thomas Clement 《社会与自然资源》2014,27(8):850-866

Social scientists have debated how affluence impacts carbon emissions at the national level. We conduct an exploratory study at the subnational level to expose another dimension of the affluence–emissions debate. Based on the notion of aristocratic conservation, we hypothesize that affluence is positively related to carbon emissions from consumption activities but negatively related to emissions from production activities. We test these hypotheses using county-level data in the United States for the year 2002. A spatial regression analysis demonstrates that median household income is positively associated with consumption-based emissions; nevertheless, we find evidence of an environmental inequality Kuznets curve in the relationship between median household income and production-based emissions. This finding suggests that the wealthiest counties are able to displace certain types of emissions, specifically those related to energy and industrial production. We discuss the theoretical and political implications of these results.  相似文献   

Tropical and extratropical cyclone damages under climate change     

Matthew Ranson  Carolyn Kousky  Matthias Ruth  Lesley Jantarasami  Allison Crimmins  Lisa Tarquinio 《Climatic change》2014,127(2):227-241

This paper provides the first quantitative synthesis of the rapidly growing literature on future tropical and extratropical cyclone damages under climate change. We estimate a probability distribution for the predicted impact of changes in global surface air temperatures on future storm damages, using an ensemble of 478 estimates of the temperature-damage relationship from nineteen studies. Our analysis produces three main empirical results. First, we find strong but not conclusive support for the hypothesis that climate change will cause damages from tropical cyclones and wind storms to increase, with most models predicting higher future storm damages due to climate change. Second, there is substantial variation in projected changes in losses across regions. Potential changes in damages are greatest in the North Atlantic basin, where the multi-model average predicts that a 2.5 °C increase in global surface air temperature would cause hurricane damages to increase by 63 %. The ensemble predictions for Western North Pacific tropical cyclones and European wind storms (extratropical cyclones) are +28 % and +23 %, respectively. Finally, our analysis shows that existing models of storm damages under climate change generate a wide range of predictions, ranging from moderate decreases to very large increases in losses.  相似文献   

Downscaling reveals diverse effects of anthropogenic climate warming on the potential for local environments to support malaria transmission     

Krijn P. Paaijmans  Justine I. Blanford  Robert G. Crane  Michael E. Mann  Liang Ning  Kathleen V. Schreiber  Matthew B. Thomas 《Climatic change》2014,125(3-4):479-488

The potential impact of climate warming on patterns of malaria transmission has been the subject of keen scientific and policy debate. Standard climate models (GCMs) characterize climate change at relatively coarse spatial and temporal scales. However, malaria parasites and the mosquito vectors respond to diurnal variations in conditions at very local scales. Here we bridge this gap by downscaling a series of GCMs to provide high-resolution temperature data for four different sites and show that although outputs from both the GCM and the downscaled models predict diverse but qualitatively similar effects of warming on the potential for adult mosquitoes to transmit malaria, the predicted magnitude of change differs markedly between the different model approaches. Raw GCM model outputs underestimate the effects of climate warming at both hot (3-fold) and cold (8–12 fold) extremes, and overestimate (3-fold) the change under intermediate conditions. Thus, downscaling could add important insights to the standard application of coarse-scale GCMs for biophysical processes driven strongly by local microclimatic conditions.  相似文献